Inkqubo yobugcisa eneenkcukacha zegraphite electrode

Iimathiriyeli ekrwada: Zeziphi izinto ezisetyenziselwa ukwenziwa kwekhabhoni?

Kwimveliso yekhabhoni, izinto ezisetyenziswa rhoqo zinokwahlulwa zibe yi-carbon eqinileyo kunye ne-binder kunye ne-ejenti yokumitha.
Izinto zekhabhoni eziqinileyo ziquka i-petroleum coke, i-coke ye-bituminous, i-coke ye-metallurgical, i-anthracite, i-graphite yendalo kunye ne-graphite scrap, njl.
I-Binder kunye ne-ejenti yokumitha ibandakanya i-pitch yamalahle, i-tar yamalahle, ioli ye-anthracene kunye ne-synthetic resin, njl.
Ukongezelela, ezinye izinto ezincedisayo ezifana nesanti ye-quartz, iincinci ze-coke ze-metallurgical kunye ne-coke powder nazo zisetyenziselwa ukuvelisa.
Ezinye iimveliso ezikhethekileyo zekhabhoni kunye ne-graphite (ezifana ne-carbon fiber, i-carbon activated, i-pyrolytic carbon kunye ne-pyrolytic graphite, i-glass carbon) ziveliswa kwezinye izinto ezikhethekileyo.

Ukubala: Yintoni i-calcination? Zeziphi iimathiriyeli ekrwada ezifuna ukubalwa?

Ubushushu obuphezulu bezinto eziluhlaza zekhabhoni zodwa emoyeni (1200-1500°C)
Inkqubo yonyango lobushushu ibizwa ngokuba yi-calcination.
I-calcination yinkqubo yokuqala yonyango lokushisa kwimveliso yekhabhoni. Ukubala kubangela uluhlu lweenguqu kwisakhiwo kunye neempawu zomzimba kunye neekhemikhali zazo zonke iintlobo zezinto eziluhlaza zekhabhoni.
Zombini i-anthracite kunye ne-petroleum coke ziqulethe umlinganiselo othile wezinto eziguquguqukayo kwaye zifuna ukubalwa.
I-coke eyenza iqondo lokushisa le-bituminous coke kunye ne-metallurgical coke liphezulu (ngaphezu kwe-1000 ° C), elilingana neqondo lokushisa lomlilo we-calcining kwisityalo sekhabhoni. Ayinakuphinda ibale kwaye idinga kuphela ukomiswa ngomswakama.
Nangona kunjalo, ukuba i-coke ye-bituminous kunye ne-petroleum coke zisetyenziswe kunye phambi kokuba zenze i-calcining, ziya kuthunyelwa kwi-calciner ukuze kufakwe i-calcining kunye ne-petroleum coke.
Igraphite yendalo kunye nekhabhoni emnyama ayifuni calcination.
Ukubumba: Uthini umgaqo wokwenziwa kwe-extrusion?
Ingundoqo yenkqubo ye-extrusion kukuba emva kokuba i-paste idlule kwi-nozzle yesimo esithile phantsi koxinzelelo, ihlanganiswe kwaye ikhubazeke ngeplastiki ibe yinto engenanto kunye nesimo esithile kunye nobukhulu.
Inkqubo yokubumba i-extrusion yinkqubo yokuguqulwa kweplastiki ye-paste.

Inkqubo ye-extrusion ye-paste iqhutyelwa kwigumbi lezinto eziphathekayo (okanye i-cylinder yokunamathisela) kunye nesetyhula ye-arc nozzle.
Intlama eshushu kwigumbi lokulayisha iqhutywa yi-plunger yangasemva.
I-gas kwi-paste iphoqeleka ukuba ikhutshwe ngokuqhubekayo, i-paste ihlanganiswe ngokuqhubekayo kwaye i-paste iqhubela phambili ngexesha elifanayo.
Xa i-paste ihamba kwindawo ye-cylinder yegumbi, i-paste inokuthathwa njengokuhamba okuzinzile, kwaye i-granular layer ihambelana ngokusisiseko.
Xa intlama ingena kwindawo yomlomo we-extrusion kunye ne-arc deformation, intlama ekufutshane nodonga lomlomo ixhomekeke ekuchaseni ukukhuhlana kwangaphambili, izinto ziqala ukugoba, intlama yangaphakathi ivelisa isantya sangaphambili esahlukileyo, intlama yangaphakathi ingaphambili. kwangaphambili, okukhokelela kwimveliso ecaleni koxinzelelo lweradial ayifani, ngoko ke kwibhloko ye-extrusion.

Uxinzelelo lwangaphakathi olubangelwa yisantya esahlukileyo semigangatho yangaphakathi nangaphandle iveliswa.
Ekugqibeleni, i-paste ingena kwi-linear deformation inxalenye kwaye ikhutshwe.
Ukubhaka
Yintoni ukuqhotsa? Yintoni injongo yokosa?

Ukugcoba yinkqubo yonyango lokushisa apho iimveliso ezixinzelelweyo zifudumala ngezinga elithile phantsi kwemeko yokwahlula umoya kwindawo yokukhusela kwisithando somlilo.

Injongo yokuxhasa yile:
(1) Ungazibandakanyi izinto eziguquguqukayo Kwiimveliso ezisebenzisa i-asphalt yamalahle njengesibophelelo, malunga ne-10% eguquguqukayo ikhutshwa ngokubanzi emva kokugcadwa. Ngoko ke, izinga leemveliso ezigcadiweyo lingaphantsi kwama-90%.
(2) Binder coking iimveliso ekrwada zosiwe ngokweemeko ezithile zobuchwepheshe ukwenza isibophelelo coking.A coke womnatha wenziwa phakathi amasuntswana aggregate ukudibanisa ngokuqinileyo yonke aggregate kunye nobungakanani amasuntswana ezahlukeneyo, ukuze imveliso ibe iimpawu ezithile ngokwasemzimbeni kunye nemichiza. .Ngaphantsi kweemeko ezifanayo, ukuphakama kwezinga lokupheka, bhetele umgangatho.Izinga lokupheka eliphakathi - i-asphalt yeqondo lokushisa malunga ne-50%.
(3) Ifomu yejometri esisigxina
Kwinkqubo yokugcoba yeemveliso eziluhlaza, i-phenomenon of softening and binder migration yenzeke.Ngokonyuka kweqondo lokushisa, inethiwekhi ye-coking yenziwe, okwenza iimveliso zibe lukhuni.Ngoko ke, imilo yayo ayitshintshi njengoko ukushisa kuphakama.
(4) Nciphisa ukuxhathisa
Kwinkqubo yokutshisa, ngenxa yokupheliswa kwezinto eziguquguqukayo, i-coking ye-asphalt yenza igridi ye-coke, ukubola kunye ne-polymerization ye-asphalt, kunye nokwakhiwa kwenethiwekhi enkulu ye-hexagonal carbon ring plane, njl., ukuxhatshazwa kwehle kakhulu. Malunga ne-10000 x 10-6 iimveliso eziluhlaza ukuxhathisa Ω "m, emva kokutshisa nge-40-50 x 10-6 Ω" m, ebizwa ngokuba ngababonisi abalungileyo.
(5) Okunye ukucuthwa komthamo
Emva kokugcoba, imveliso iyancipha malunga ne-1% ububanzi, i-2% ubude kunye ne-2-3% yevolumu.
Indlela yokuphucula: Kutheni uthengisa iimveliso zekhabhoni?
Imveliso ekrwada emva kokubunjwa koxinzelelo ine-porosity ephantsi kakhulu.
Noko ke, emva kokugcadiswa kweemveliso ezikrwada, inxalenye ye-asphalt yamalahle iboliswa ibe yigesi kwaye ibaleke, kwaye enye inxalenye igalela kwi-bituminous coke.
Umthamo we-coke ye-bituminous eyenziwe yincinci kakhulu kune-bitumen yamalahle. Nangona iyancipha kancinci kwinkqubo yokugcoba, iipore ezininzi ezingaqhelekanga kunye ezincinci ezinobukhulu obahlukeneyo bobupore zisabumba kwimveliso.
Umzekelo, i-porosity iyonke yeemveliso ezenziwe ngegraphiti ngokubanzi ukuya kuthi ga kwi-25-32%, kunye neemveliso zekhabhoni zihlala zi-16-25%.
Ubukho benani elikhulu le-pores liya kuchaphazela ngokuqinisekileyo iipropati ezibonakalayo kunye neekhemikhali zeemveliso.
Ngokubanzi, iimveliso zegraphiti kunye nokunyuka kwe-porosity, ukuxinana kwevolumu ehlileyo, ukonyuka kokumelana, amandla omatshini, kwiqondo elithile lobushushu besantya se-oxidation liyakhawuleza, ukuxhathisa umhlwa kuyehla, igesi kunye nolwelo lungena lula.
I-Impregnation yinkqubo yokunciphisa i-porosity, ukwandisa ukuxinana, ukwandisa amandla okunyamezela, ukunciphisa ukuxhathisa kwemveliso egqityiweyo, kunye nokutshintsha iimpawu ezibonakalayo kunye neekhemikhali zemveliso.
IGraphitization: Yintoni igraphitization?
Yintoni injongo yegraphitization?
IGraphitization yinkqubo yonyango lobushushu obuphezulu kusetyenziswa iimveliso ezibhakiweyo ukufudumeza ukuya kubushushu obuphezulu kwindawo ekhuselayo yesithando somlilo ukwenza igridi yenqwelo moya ye-athomu enehexagonal iguqule ukusuka ekudibaneni okungacwangciswanga kwindawo enemigangatho emibini ukuya kucwangco kwindawo enemigangatho emithathu kwaye ngesakhiwo segraphite.

Iinjongo zayo zezi:
(1) Ukuphucula i-thermal kunye ne-conductivity yombane yemveliso.
(2) Ukuphucula ukuxhathisa ubushushu kunye nokuzinza kweekhemikhali zemveliso.
(3) Ukuphucula i-lubricity kunye nokunxiba ukuxhathisa kwemveliso.
(4) Susa ukungcola kwaye uphucule amandla emveliso.

Umatshini: Kutheni iimveliso zekhabhoni zifuna ukwenziwa ngoomatshini?
(1) Imfuneko yotyando lweplastiki

Iimveliso zekhabhoni ezixinzelelweyo ezinobungakanani obuthile kunye nokumila zineedigri ezahlukeneyo zokuguqulwa kunye nomonakalo wokungqubana ngexesha lokutshisa kunye negraphitization. Ngexesha elifanayo, ezinye iifayili ziboshwe phezu kweemveliso zekhabhoni ezixinzelelweyo.
Ayinakusetyenziswa ngaphandle kokulungiswa komatshini, ngoko ke imveliso kufuneka ibunjwe kwaye iqhutywe kwimilo yejometri ecacisiweyo.

(2) Imfuneko yokusetyenziswa

Ngokweemfuno zomsebenzisi zokusetyenzwa.
Ukuba i-electrode yegraphite yesithando sombane somlilo kufuneka idityaniswe, kufuneka yenziwe ibe ngumngxuma odibeneyo kuzo zombini iziphelo zemveliso, kwaye ke ii-electrode ezimbini kufuneka zidityaniswe ukuze zisetyenziswe ngokudibeneyo okhethekileyo.

(3) Iimfuno zobuchwepheshe

Ezinye iimveliso kufuneka ziqwalaselwe ngokwemilo ekhethekileyo kunye neenkcukacha ngokweemfuno zobuchwepheshe zabasebenzisi.
Noburhabaxa bomphezulu obusezantsi buyafuneka.


Ixesha lokuposa: Dec-10-2020